I run my radion pro's overall brightness at 75% on a 31" deep tank...just upped it from 70% after noticing some rock nems starting to crawl up my rocks from the sandbed. Blues and UV do peak at 100%, but the whites only peak at 55% mid-day.
The schedule that you are considering is essentially how I have mine programmed; I adjusted the levels slightly from the 14k setting (decreased the reds and greens, increased white slightly), but I have a 2 hour period in the middle of the day where my tank is at 14k.
I would lower your intensity significantly (65-70%), program that mid-day "burst" with increased whites, and use the acclimation setting to gradually increase your intensity over several weeks. You should eventually find a "sweet spot" where the corals are looking happy for at least a few days before the start getting too much light and react poorly. IMO, that approach will be less abrupt of a change than hitting them with a sudden increase in your white LEDs...even if it's only for 15 minutes initially, it's potentially still enough for some of your corals to start shedding zooxanthellae and bleach if they are stressed.
I attached my schedule if you want to check it out, just have to unzip the .etg file