True, copper does transfer the heat better, but only slightly better. Pex is used alot in radiant heating systems in some houses, where they run coils of pex under the floor boards. Pex is used specifically because it transfers heat so well, and is non conductive. The only better option to pex lines is Titanium, and well thats a bit out my price range, as it would likely cost somewhere between $5000 or so to have a titanium coil made
There is about 50-60 ft worth of pex for each coil. I basically put as much as I could down there without taking up to much space in the chamber. I calculated it once when I was first planning, and I determined that 30-35 ft of tubing was the minimum amount required. By increasing the amount of surface area with more tubing, it should make it more efficient overall, as it will ensure full transfer of heat before the water reaches the end of the coil.